Product ID:1-PROPANOL (N-PROPYL ALCOHOL,(SEE SUPP DA)
MSDS Date:06/24/1989
FSC:6810
NIIN:01-119-7846
MSDS Number: BLLCL

FISHER SCIENTIFIC,CHEMICAL DIVISION

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100 DAY;(SEE SUPP DATA)

Info Phone: 201-796-7100

Preparer: GASTON PILLORI (CONTACT)

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

N-PROPYL ALCOHOL

CAS: 71-23-8

RTECS: UH8225000

Fraction By Weight: 100%

OSHA PEL 200 PPM/250 STEL

ACGIH TLV: S,200PPM/250STEL9192

OF STOR TANK DUE TO FIRE.EXTING ONLY IF

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

& TO COOL CONTR.APPLY FROM AS FAR AWAY AS

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

RUBBER

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

VIOLENT RXN W/ POTASSIUM

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

UNNECESSARY PERS AWAY.ISOLATE HAZ.DENY ENTRY.EYE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

SFTY

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 RAT ORAL 1870 MG/KG;(SEE ING 5)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:REPEATED OR PROLONGED EXPOSURE MAY
CAUSE DERMATITIS AND POSSIBLE CORROSION AND/OR
CONJUNCTIVITIS.INGEST/INHAL:MAY CAUSE OLIGURIA FOLLOWED BY DIURESIS
AND LIVER DAMAGE,BRAIN AND LUNG EDEMA.USE OF ALCOH OLIC BEVERAGES
MAY ENHANCE TOXIC EFFECTS.TOXIC BY SKIN ABSORPTION.
Explanation of Carcinogenicity:NONE
Effects of
Overexposure:EYES:IRRITATION,REDNESS,PAIN.SKIN:IRRITATION,REDNESS.C
HRONIC:DEFAT,DRYING,CRACKING.POISONING DUE TO SKIN
ABSORPTION.INGESTION:CRAMPS,DIARRHEA,DECREASED BLOOD PRESSURE,CNS
DEPRESSION.ASPIRATION HAZARD. INHAL:IRRITATION,COUGH,SHORTNESS OF
BREATH,CNS DEPRESSION.HIGH CONCENTRATIONS:DEATH BY RESPIRATORY
FAILURE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS,IMPAIRED LIVER,RENAL &/OR PULMONARY FUNCTION.PERSONS
SENSITIVE TO ISOPROPYL ALCOHOL MAY HAVE A CROSS-REACTION WITH
N-PROPYL ALCOHOL.

First Aid:EYES:WASH IMMED W/ H*2O OR SALINE OCCASNLY LIFTING LIDS
(APPROX 15-20 MIN).GET MED ATTN.REMOVE CONTAM CLTHG & SHOES.WASH W/
SOAP OR MILD DETERGENT & LG AMT OF H*2O (APPROX 15-20 MIN).GET MED
ATTN.INGE STION:GIVE ACTIVATED CHARCOAL.GASTRIC LAVAGE MAY BE
USEFUL.GIVE OXYGEN.MAINTAIN BLOOD PRESS.INHALATION:MOVE TO FRESH
AIR IMMED.KEEP WARM & AT REST.IF BRTHG STOPPED,GIVE ARTF RESP.GET
MED ATTN IMMED.

Flash Point Method:CC
Flash Point:74F,23C
Autoignition Temp:Autoignition Temp Text:775 F
Lower Limits:2.2%
Upper Limits:13.7%
Extinguishing Media:DRY CHEM,CARBON DIOXIDE,HALON,H*2O SPRAY/ALCOHOL
FOAM.LG FIRE:H*2O SPRAY,FOG OR ALCOHOL FOAM.WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:MOVE CONTR FROM FIRE AREA IF POSS.COOL
FIRE-EXPOS CONTR W/ H*2O FROM SIDE UNTIL WELL AFTER FIRE IS
OUT.STAY AWAY FROM STOR TANK ENDS.MASSIVE FIRE IN (SEE SUPP)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ,MOD EXPLO HAZ IF EXPOS
TO HEAT/FLAME.VAP HEAVIER THAN AIR,MAY TRAVEL TO IGNIT SOURCE &
FLASH BACK.VAPOR-AIR MIX EXPLOSIVE ABOVE FLASH POINT.

Spill Release Procedures:SHUT OFF IGNITION SOURCE.STOP LEAK IF W/O
RISK.USE WATER SPRAY TO REDUCE VAPOR.SM SPILL-TAKE UP W/ SAND OR
OTHER ABSORB MATL.PLACE IN CONTR FOR DISP.LG SPILL:DIKE FAR AHEAD
OF SPILL FOR LATER DISP.NO SMKNG/FLAME/FLARES IN HAZ AREA.KEEP
(SEE ING 6)
Neutralizing Agent:N/K

Handling and Storage Precautions:OBSERVE ALL FED,STATE & LOCAL REGS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE.CONTACT THE DISTRICT
DIRECTOR OF THE EPA.STORE IAW 29 CFR 1910.106.
Other Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES.BONDING &
GROUNDING:SUBSTANCES WITH LOW ELECTROCONDUCTIVITY,WHICH MAY BE
IGNITED BY ELECTROSTATIC SPARKS,SHOULD BE STORED IN CONTR MEETING
NFPA 77-1983 REC PRAC TICE ON STATIC ELECTRICITY.

Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED
ON CONTAMINATION LEVELS IN THE WORKPLACE AND BE JOINTLY APPROVED BY
NIOSH/MSHA.
Ventilation:PROVIDE GENERAL DILUTION VENTILATION TO MEET PUBLISHED
EXPOSURE LIMITS.VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:WEAR APPROP GLOVES TO PVNT SKIN CONTACT.
Eye Protection:SPLASH-PROOF/DUST-RESISTANT (SEE ING 7)
Other Protective Equipment:WEAR APPROP IMPERVIOUS CLTHG & EQUIP TO PVNT
RPTD/PRLNG SKIN CONT.IF EYE/SKIN CONT POSS:EYE WASH,QUICK DRENCH
SHOWER.
Work Hygienic Practices:N/K
Supplemental Safety and Health
PART NO:ETHYL CARBINOL).EMER PHONE NO:201-796-7523 (NIGHT);800-429-9300
(CHEMTREC).SOLUBLE IN ETHANOL,ETHYL ETHER,ACETONE,BENZENE.FIRE
FIGHT PROC:STOR AREA-USE UNMANNED HOSE HOLDER/MONITOR NOZZ,ELSE W
ITHDRAW FROM AREA & LET FIRE BURN.WITHDRAW IMMED IF RISING SOUND
FROM VENTING SFTY DEVICE/ANY DISCOLORATION (SEE ING 2)

Boiling Pt:B.P. Text:207F,97C
Melt/Freeze Pt:M.P/F.P Text:-195F,-126C
Decomp Temp:Decomp Text:N/K
Vapor Pres:15 MMHG
Vapor Density:2.1,AIR=1
Spec Gravity:0.8053 (H*2O=1)
Viscosity:2.256CP AT20C
Evaporation Rate & Reference:1.3,BUTYL ACETATE=1
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID;MILD ALCOHOL-LIKE,SLIGHTLY
STUPEFYING ODOR.

Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY W/ ALKALI & ALKALINE EARTH METALS GENERATING HIGHLY
FLAMM HYDROGEN GAS.COATINGS,PLASTICS & (SEE ING 4)
Stability Condition to Avoid:HEAT,SPARKS,FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.

Waste Disposal Methods:DISP MUST BE IAW FED,STATE & LOC
REGS.COORDINATION W/ SUPPORTING INSTALLATION &/OR MACOM
ENVIRONMENTAL COORDINATION PRIOR TO DISP IS REC TO DETERMINE APPROP
DISP METH .FOR ASSISTANCE,CONTACT THE DISTRICT DIRECTOR OF THE
ENVIRON PROT AGENCY.

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.